Scientific Reports volume 12, Article number: 20053 (2022 ) Cite this article Aluminium Oxide Powder
Mg–Al–Zn alloys are widely preferred in many applications by considering their excellent properties of high stiffness-to-weight ratio, lightweight, high strength-to-weight ratio, low density, castability, high-temperature mechanical properties, machinability, high corrosion resistance, and great damping. Improving the properties of such alloys is challenging due to their hexagonal crystal structure and other alloying limitations. This study aims to synthesize Mg–Al–Zn alloy by incorporating the alloying elements 8.3 wt% Al, 0.35 wt% Zn on pure magnesium (Control specimen). Then synthesize Mg–Al–Zn/BN/B4C hybrid composite by reinforcing B4C at three weight proportions (3 wt%, 6 wt%, 9 wt%) along with constant solid lubricant BN (3 wt%) through a stir casting process. The hybrid composite samples were characterized and compared with the performances of the control specimen. The results reveal that 9 wt% B4C reinforced samples outperformed through recording the improvement of tensile strength by 28.94%, compressive strength by 37.89%, yield strength by 74.63%, and hardness by 14.91% than the control specimen. Apart from this, it has reduced the corrosion area (37.81%) and noticed negligible changes in density (increased by 0.03%) and porosity (decreased by 0.01%) than the control specimen. The samples were characterized using SEM, XRD, and EDAX apparatus.
Low-density materials are becoming more prevalent in automotive, aerospace, and marine applications due to their less dense and higher energy efficiency. Compared with other metals and alloys, magnesium and its alloys have gained interest due to their less dense performance and high compressive strength. Further, magnesium is recyclable with a reduction in the emission of CO2 is another important reason for fulfilling functional applications1. Despite their excellent physical properties, these materials have limited applications due to low strength, modulus, and wear resistance, are highly reactive, and have poor creep resistance at high temperatures2. These disadvantages can be removed by adhering to desired processing methods and adding alloying elements or reinforcement3. Based on the presented results, ceramics such as Silicon carbide, Aluminium oxide, Boron carbide, Silicon nitride, Titanium dioxide, Aluminium nitride, Titanium nitride, Yettrium oxide, and Titanium carbide have been used to strengthen particulates that are composed of magnesium composites4.Ceramic reinforcements can be encapsulated with a matrix material, leading to limitations. Increasing the weight fraction of unique ceramic reinforcing particles in the matrix material increased hardness, density, toughness, and brittleness, but decreased ductility and elongation percentage was observed5. This is due to the matrix alloy’s homogenous distribution of strengthening particulates, while agglomeration results in inferior properties6. The literature studies determined that the inclusion of the secondary ceramic particulate in the parent material strengthens the material through a reduction in grain size, determines the mechanical properties of composites, and is affirmed as a hybrid composite. Numerous studies have been conducted on synthesizing magnesium hybrid composites using different processing methods and reinforcements7. The powder metallurgy approach was used to characterize the worn performance of magnesium composites. The inclusion of Graphite extended the wear resistance of hybrid mixtures and reduced the microhardness properties8. The semisolid stirring method was employed to develop the dynamic tensile behaviour of magnesium hybrid nanocomposites. It was observed that the strain rate hardening was distinct at different temperatures when Nanoscale SiC and MWCNT were used for reinforcement9. The inclusion of SiC particles effectively improved the wear rate of synthesized composites due to the reinforcement of short fibres and cast composites using the squeeze casting method10. Liquid metallurgy has been used to develop boron carbide’s mechanical properties and graphite’s toughened magnesium intermix complexes. Incorporating graphite into matrix alloy results in a decrease in wear characteristics11. Microstructure and physical properties of aluminium hybridized composites were examined using titanium diboride and boron nitride as strengthening parts, with the inclusion of BN having the primary purpose of enhancing wettability while enhancing wear resistance12. Based on the literature, it has been concluded that the density has significantly influenced the choice of reinforcement for synthesizing magnesium alloy hybrid composites. If otherwise, the density of such combinations would increase and be mismatched with the weight reduction properties for functional applications13. As part of the proposed innovative study, ceramic reinforcements with low-density materials have been chosen for the continued development of magnesium alloy hybrid composites. A literature study was performed for the explicative research gap, and some implications for this study were summarized. Mg–Al–Zn alloys have a hexagonal crystal structure, which affects fundamental properties such as toughness, flexibility and other properties. Aside from that, the surface energy of this material is high compared to other lightweight materials such as aluminium or zinc. Still, it has less corrosion and wear resistance than aluminium. It was also observed that in magnesium alloys, 10 wt% Al improves tensile strength, hardness, and castability by increasing solid-solution strengthening, and 0.35% Zn forms MgZn2 phases along grain boundaries, resulting in excellent age hardening and found to provide improved characteristics. However, adding alloying elements is restricted to the base magnesium alloy, as it is integral to the material's environmental compatibility14. It was nailed that only the addition of ceramic reinforcing particles such as borides, carbides and nitrides improve the properties of Mg–Al–Zn alloys. Further investigation into the wettability of boron carbide and boron nitride with Mg–Al–Zn alloys as particulate-strengthened particles for consolidating hybridized composites was found to be lacking. Since magnesium exhibits highly reactive and forms magnesium oxide when exposed to the atmosphere, it is a major drawback of such alloys. It was forecasted that by adding low density of reinforcement to a combination of different base materials, the density of composites was restored, and its mechanical properties were notably improved15. A literal analysis found that the inclusion of B4C reinforcement of different particle sizes results in a higher mechanical strength of the material. Still, BN reinforcement is limited despite having a lower density than B4C16. It also inferred that boron carbide and boron nitride had not been extensively investigated as particulate-strengthened particles for consolidating Mg–Al–Zn alloy-based hybrid composite. The particulates recommended for reinforcement have a lower density of 2.5 g/cm3 and 2.1 g/cm3 for boron carbide and boron nitride than other ceramic reinforcements. By adding this combination of reinforcement in different base materials, the density of the final material (composite) has been restored, and its mechanical properties further improved. The effects strengthen the properties of Mg–Al–Zn alloy (91.35 wt% pure magnesium, 8.3 wt% Aluminium, 0.35 wt% Zinc) by reinforcing B4C at three levels (3 wt%, 6 wt%, 9 wt%) with constant solid lubricant BN of 3wt%. was not yet reported so far. Since BN is lamellar in a structure like molybdenum disulfide and graphite, and comparison to these, it is a better solid lubricant. Due to this factor, BN is preferred as secondary reinforcement, and its percentage weight is kept constant in the present investigation. Hence this piece of research addresses synthesizing, characterizing and testing of Mg–Al–Zn/BN/B4C hybrid composites samples and comparing their performance with synthesized as cast Mg–Al–Zn alloy (control specimens).
The novelty of the present study is synthesizing Mg–Al–Zn alloys by incorporating the alloying elements 8.3 wt% Aluminium, 0.35 wt% Zinc into pure magnesium. Then, this casted alloy was strengthened with hard ceramic strengthening particles of B4C (3 wt%, 6 wt%, 9 wt%) with solid lubricant BN (3wt%) using the bottom pouring stir casting process and compared the three Mg–Al–Zn/B4C/BN hybrid composites performances with Mg–Al–Zn alloy in terms of density, porosity, hardness, tensile strength, yield strength, percentage of elongation, compressive strength and corrosion rate, including microscopic investigations like SEM, XRD etc., for ensuring the quality of new material for marine applications such as engine casings, hulls and fins.
This work uses commercially available alloys of Mg–Al–Zn–Si–Ni to develop magnesium alloy, and the chemical constituents of these materials are outlined in Table 1. Including aluminium and zinc in magnesium alloys increases their hardness and strength at room temperature. It is believed that Mg–Al–Zn alloys are most commonly used for weight deduction at room temperature. Further, it has a high strength-to-weight ratio, good flexibility, better damping properties, and excellent castability. It is ideal as a matrix material for fabricating magnesium hybrid composites17. The reinforcements B4C of (~ 1 µm) and BN (< 10 µm) of particle size from Sigma Aldrich are also used to incorporate such composites.
The Stir casting apparatus of the bottom pouring type is used to produce magnesium alloy hybrid composite materials with an inert gas environment, as shown in Fig. 1a. The die used for casting magnesium alloy hybrid composites is shown in Fig. 1b, and the fabricated samples of Mg–Al–Zn alloy composites are presented in Fig. 1c. To make magnesium melt, the resistance heating furnace is initially preheated to 250 °C, followed by placing the required amount of casted magnesium alloy in the furnace and melting it for 45 min before the temperature is raised to 750 °C. Through external spruce, the reinforcement of B4C particles of varying their weight percentage (3wt%, 6wt%, and 9wt %) and keeping constant of BN (3wt %) is added into the melt. To prevent oxidation and burning, 3.5 l/min of a CO2 and SF6 mixture was allowed to discharge into the furnace, and the melting temperature was raised to 750 °C. It was also noted that density is important in enhancing the even dispersion of ceramic particles within the base material9. The reason for that is that if the density of reinforcement is minimal, it will remain alone at the top of the molten slurry, whereas if the density is maximal, it will settle down to the bottom. By using an effective process parameter, this problem can be resolved.
(a) Stir casting apparatus (b) Die used for synthesizing magnesium alloy hybrid composites (c) Samples of Mg–Al-Zn alloy.
For effective stirring, the stirrer diameter must also be considered. The solid particles remain suspended at the outside edge of the vessel when the stirrer diameter is too small and can remain in the vessel’s centre if it is too large. As a result, the stirrer diameter has been set to 0.4D, per the literature citation19. A parameter associated with the stir casting method must be considered to achieve homogenous particle distribution in the matrix alloy. Due to this, the stirring speed and stirring time were maintained at 600 rpm and 15 min, as cited in the literature20. It was found that pouring temperature significantly affects particle distribution. Higher melt temperatures tend to float the ceramic particles to the surface of the melt, while lower melt temperatures reduce melt viscosity and make casting more difficult21. Owing to these facts, the optimal temperature for casting magnesium alloy hybrid composites was maintained at around 700 °C for pouring the molten slurry into the die cavity. An EN24 die with a diameter of 0.022 m and a length of 0.2 m is placed in the bottom of the apparatus and coated with sulfur powder to prevent oxidation and burning of the molten slurry. Then, the molten slurry is poured into the die and left to cool at atmospheric pressure in the die alone. The same procedure has been repeated using different reinforcement weight percentages and synthesizing magnesium alloy hybrid composites.
The increase of low-density ceramic particulates (B4C) up to a maximum of 12 wt% in molten magnesium alloy cause agglomeration even when stirring is applied to obtain a homogeneous distribution of such particulates in the matrix. This cannot be achieved because a few unwetted ceramic particles that float on the melt surface will stick together and accumulate in one region, giving it poor mechanical properties. Utilizing a higher percentage of ceramic particulates in the cast magnesium composite increases its porosity, forming a SiO2 layer on top of the ceramic particulates as they are filled with molten slurry. It was noted that when the number of reinforcing particles increased to the maximum, the percentage of clusters increased along several regions of the base material leading to pores and a gas layer surrounding the ceramic particles causing clusters to float. As a result, the weight percentage has been limited to 9wt%, and the results of the synthesized hybrid mixtures were discussed in Xiang et al.22.
Performance measures for magnesium alloy hybrid composites were prepared using ASTM standards. A De-Winter trinocular inverted metallurgical microscope is used to characterize the microstructure of synthesized composites. The density of synthetic composites has been calculated using Archimedes principles with ethanol as suspending medium. Using Wilson Wolpert Germany, a micro Vickers hardness test is used to determine the microhardness of materials under a 1 kg load. Using a universal testing machine, the ASTM E8 standard is used to study the tensile behaviour of hybridized mixtures. The maximum load range is 10 tons, and the shear rate is 0.5 m/min. For evaluating the compressive strength of an intermixture at room temperature, the ASTM E9 standard is used. The corrosion resistance of hybridized composite composites has been analyzed using the B117 salt spray test23.
An optical microscope is used to characterize the finely structured magnesium alloy hybrid composites. Figure 2a to Fig. 2f examine the as-cast and etched hybridized composites with differing percentages of boron carbide and boron nitride by weight. Picral is used as the etching agent24. The microstructure of both B4C and BN reveals the homogenous distribution of strengthening particles without any evidence of a cluster. Moreover, the higher inclusions of B4C particulates in the parent material display the primary magnesium grains and appear finer. Due to impurities, grain boundaries of newly synthesized hybrid composites show microparticles of eutectic precipitates. Boron carbide has a larger granularity than boron nitride, so the distribution of BN is leaned and appears as dull shiny white particles due to the inferior inclusion of BN in the matrix alloy. It was presumed that the microstructures of the synthesized magnesium alloy hybrid composites possessed B4C, Mg, MgO and MgB2 interphases. This is because increasing the proportion of boron carbide increases the formation of the MgO and MgB2 phases due to the heating process and reactions between the immixtures24. The microstructural studies found that good interfacial integrity between the Mg matrix and the hybrid ceramic reinforcement was esteemed regarding the nonappearance of voids and debonding at the particle–matrix interface. This stimulates the enhancement of the mechanical properties of synthesized magnesium alloy hybrid composites, as inferred in similar findings25.
(a–f). Microstructure of Mg–Al-Zn Alloy composite strengthened with boron carbide of varying weight proportions and boron nitride constant.
The morphology characteristics of magnesium alloy hybrid composites and the distribution of ceramic reinforcement particles are analyzed using SEM, as shown in Fig. 3a,b. It was determined that B4C appears as a needle-like structure within the magnesium alloy matrix which is constantly dissipating through regions of grain boundaries and internal grain boundaries. Because of the pinning effect, BN acts as nucleation sites and reduces grain size while causing a reduction in grain growth due to the higher proportion of grain boundary particles in the matrix alloy26.
SEM image of Mg–Al–Zn Alloy composite strengthened with (a) 6wt% boron carbide and 3% boron nitrate, (b) 9wt% boron carbide and 3% boron nitrate, (c) XRD image of Mg–Al-Zn Alloy composite strengthened with 9% boron carbide and 3% boron nitrate, (d) EDAX analysis of the image of Mg–Al-Zn Alloy composite strengthened with 9% boron carbide and 3% boron nitrate.
The interfacial reaction plays a vital role in increasing the mechanical properties of magnesium hybrid composites. The presence of boron carbide interacts with Mg–Al–Zn magnesium alloy and forms the intermetallic components of Mg17Al12, MgB2, Mg2Si, Mg3BN3, MgO, B2O3, MgC2 as shown in Fig. 3c as inferred in the literature27. In the XRDA, two major principal peaks are observed in the intermixture, such as Mg and B4C, which resulted in small molecules of MgO being formed by the partial reaction of Mg with oxygen. In contrast, MgC2 is formed by reaction with free carbon in the system, but this phase is unstable and rapidly deteriorates28. Also, it was observed that molten magnesium reacts with B4C to form magnesium diboride, which liberates elemental carbon. The presence of MgB4 peaks in the XRD pattern proved that MgB2 partially decomposes to form MgB4, which agrees with similar findings29. It was also found that it accommodates heterogeneous nucleation sites during solidification, hence reducing grain size in the matrix alloy. This acts as a strengthening mechanism of fabricated magnesium alloy intermixture30.
The EDAX analysis of the Mg–Al–Zn alloy hybrid intermixtures shown in Fig. 3d indicates that the major elements are Mg, Al, B, Si, N, and some oxides. Observations have shown that particle Si in a matrix continues to react with Mg to form Mg2Si31. As a result of the presence of Mg2Si, the mechanical properties of the developed Mg–Al–Zn alloy immixture are enhanced, and this compound contains a mixture of Mg–Al–Si–Mn–B–N compositions.
It seems important to measure the density of synthesized magnesium alloy hybrid composites because they contain ceramic strengthening particles with a density considerably higher than the base material. A higher density of magnesium alloy reinforcement will result in a higher density of synthesized composites. This has detrimental effects on the perception of weight reduction properties. Considering those factors, the density and porosity of high-density magnesium alloy hybrid composites have been measured using the rule of mixture equation. In contrast, their experimental density has been measured using Archimedes' principle with ethanol as a suspending medium. Eqs. (1) and (2) give a formula for calculating magnesium alloy hybrid composites' theoretical density and porosity32.
Owing to the accession of superior density particulates in the heterogeneous mixture, strengthening in the proportion of reinforcement, and the existence of interfacial reaction between the matrix and reinforcement, the density of the Mg–Al–Zn alloy hybrid is increased substantially to a minimum of 0.038% compared with monolithic magnesium alloy as inferred in Fig. 4. Increasing the percentage of binary ceramic particulates significantly reduces the porosity of actualized composites33. Moreover, ceramic strengthening particles added to the molten alloy caused the particles to accumulate at the melt surface, even after mechanical stirring mixed the reinforcement particles29. The majority of these particles tried to stick together once the stirring stopped. However, the reduced viscosity of these particles caused them to remain in the matrix area, which resulted in a uniform dispersion throughout the matrix. This is due to a reduction in the entrapment of gas particles while adding the hybrid reinforcement particles in the molten melt and minimization of the shrinkage effect at the time of solidification. This contributes to the increased compressive properties of developed magnesium alloy hybrid composites.
Density and porosity of Mg–Al–Zn alloy hybrid composites.
The hardness of hybrid composites developed by varying the proportion of B4C and keeping the BN reinforcement is shown in Fig. 5. Compared with monolithic magnesium alloys, it is shown that the addition of ceramic reinforcement increases the hardness of hybrid composites to an optimum of 14.91%. This is due to factors such as the uniform distribution of ceramic particulates inside the parent material, the presence of hard interface particles, and the large difference in thermal expansion coefficient between the matrix and reinforcement that significantly increased the dislocation density in the microstructures of synthesized composites as reported in the literature34. Furthermore, the combination of ceramic strengthening particulates in the magnesium alloy matrix increases boron carbide throughout the regions and reduces the matrix grains. Consequently, a large increase in grain boundaries, which act as obstacles to dislocations, causes an increase in the microhardness of synthesized hybrid composites, as inferred in the literature35. In addition, the inclusion of secondary reinforcement solid lubricant (BN) assists in increasing the hardness of the synthesized composites and acts as a barrier, along with the B4C, in preventing the passage of dislocation during indentation.
Hardness of magnesium alloy hybridized composites.
In this study, it has been observed from Fig. 6a that by enhancing the proportionality of hard ceramic particulates, the ultimate tensile and yield strengths of the magnesium alloy heterogeneous mixture increased considerably. Still, the elongation percentage decreased, as Fig. 6b inferred.
(a) Tensile and yield strength of Mg–Al–Zn alloy hybrid composites (b) Percentage elongation of Mg–Al–Zn alloy hybrid composites (c) Compressive strength of Mg–Al–Zn alloy hybrid composites.
This occurred due to an excellent load transfer from matrix to ceramic phase, Orowan strengthening mechanism, grain refinement, and differences between the thermal and elastoplastic performance of the synthesized hybrid composites36. When the reinforcement is uniformly distributed in the magnesium matrix, it exhibits high-density dislocations. It, therefore, causes a discrepancy between the parent material and reinforcement particles, which acts as a strengthening effect when hybrid composites are strained37.
A compressive strength test was conducted as per ASTM E9 for magnesium alloy hybrid composites38. As discussed in the literature, under loading conditions, magnesium matrix materials' deformation varies for tensile properties (slip) and compressive properties (twinning)39. In contrast with Mg–Al–Zn base alloys, the compressive strength of fabricated magnesium alloy mixtures is significantly enhanced, as shown in Fig. 6c. This leads to an interfacial strength distribution throughout the magnesium matrix, a reduced twinning movement, and a refined grain structure. Observations have shown that matrix grain refinement in the Mg matrix is affected by the reinforcement and particle distribution, indicating that the uniformity of particle distribution is sufficient for grain size reduction in a hybridized magnesium alloy mixture. It is also inferred that during straining, the inclusion of secondary reinforcement would alter the strain rates of magnesium alloy hybrid composites; therefore, the fracture surface appears smooth. A heterogeneous deformation on the magnesium alloy matrix occurs at the grain boundary and, as such, inhibits plastic deformation but leaves the crystalline core of the grain when compressive loading occurs; hence the compressive properties of synthesized magnesium alloy hybridized composites significantly increase, as cited in the literature.
It has also been noted that the increased strength at room temperature is due to enhancing grain refinement, as shown in Fig. 7a,b. By increasing the hardening of matrix alloy reinforcement, crack propagation has been minimalized to its maximum when applied loads to composites. Additionally, the deformation mechanism contributes significantly to enhancing the tensile properties of magnesium alloy hybrid composites because adding aluminium and zinc elements results in less stacking fault energy reduction than among the other elements34,35,36. Furthermore, incorporating secondary reinforcement (BN) can lead to the generation of higher heterogeneous nucleation sites (Mg17Al12) and consequently lead to the greater fracture toughness of the magnesium hybrid composites. As a result, premature failure occurs if the bonding between the matrix and reinforcement is not substantial. This cannot be observed in synthesized composites.
(a,b) Grain refinement of AZ91 with 9wt% boron carbide and 3wt% boron nitrate.
Furthermore, it is found that when the percentage of reinforcement is increased, the percentage of elongation decreases significantly. Consequently, the composite may be brittle because of the lack of superplasticity produced by including hard ceramic reinforcement. It is also noted that particles forced against each other during solidification restricted the growth of the primary phase and nuclei of the AZ91D alloy.
Magnesium alloys are highly reactive in humid or wet environments due to their loosened oxide layer, which causes them to corrode much more easily in marine environments with high aqueous concentrations40. The occurrence of galvanic corrosion in magnesium alloys can also pose a problem since magnesium has the lowest electrode potential and functions as an anode. Even though alloying Al and Zn with Mg increase their strength, they are more prone to galvanic corrosion. In corrosion tests performed on Mg and AZ91 alloys using 0.1 M NaCl solutions, the AZ91 alloy displayed higher corrosion than Mg metal. The influence of alloying elements like Zr and Al on the corrosion resistance of Mg was tested electrochemically. They found that AZ91 alloy shows the worst corrosion resistance (9E−4 mm/year) among AZ31, AZ91, AM60 and ZK60 alloys40. During immersion of magnesium alloys in NaCl solution, the following reactions occur on the surface as illustrated in Eqs. (3, 4 and 5), and a similar finding was inferred in the literature41.
When magnesium comes in contact with an aqueous solution, magnesium hydroxide is formed on the magnesium surface, serving as a protective layer. However, since it is porous, this layer will not protect the alloy from corrosive mediums containing Cl. Suitable ceramic strengthening particles can be added to magnesium alloy to overcome this problem.
The developed hybrid composites’ corrosion resistance was evaluated according to the ASTM-B117 salt spray test, and the results are shown in Fig. 8. Adding hybrid reinforcement (B4C and BN) to magnesium alloys increases corrosion resistance due to galvanic coupling, interfacial phase formation, and microstructural changes between the reinforcements and matrix. Further, the corrosion rate of synthesized composites displays a two-phase microstructure consisting of a crystalline magnesium matrix with an aluminium phase (Mg17Al12) over the grain boundaries42. Hybrid composites containing eutectic phases such as Mg, Zn, and Cu show enhanced corrosion behaviour in a corrosive solution of 3.5% NaCl, which affects the volume, composition, and distribution of other eutectic phases.
The corrosion resistance of magnesium composites.
In an investigation of a hybrid composite, it has been determined that the alpha-Mg matrix, which acts as a micro cathode, stimulates corrosion at micro-scales, as found in an alpha-Mg matrix as cited in the literature43. The presence of the β phase reduces the reactive surface of hybrid composites, and, as a consequence, the amount of corrosion observed on their surfaces has been reduced. Furthermore, for each alpha grain boundary, a continuous beta phase hinders the corrosion from dispersing from one alpha grain to another, preventing corrosion from forming on the surface of α grains. Thus, the magnesium alloy hybrid composites get dissolved, and the full beta film is exposed to the solution, significantly increasing corrosion rates. From the SEM image, it is evident that the β phases appear intense. The α phase materializes finer due to its occurrence of solidification immediately at room temperature, as shown in Fig. 9. In addition, the appearance of the β phase appears narrow and continuous, thereby inhibiting the corrosion rate of the α phase uniformly through the corrosion that forms on the composites externally. It has been observed that, upon rapid cooling of these composites, they form primary grains with an irregular eutectic of α and β phase; thus, they exhibit enriched forms of eutectic of α, which limit the probability of the occurrence of essential α grains. A grain size reduction has been observed due to increasing solution concentration relative to initially formed internal α grains. The presence of fine grains is confined to being stable β phases. Fine grains are confined to being stable β phases over α grain boundaries and react as an obstacle to giving the corrosion moment an increased value, consequently decelerating.
Morphology of various phases of AZ91D + 9wt% B4C + 3wt% BN.
Based on the experimental studies, B4C/BN reinforced Mg–Al–Zn alloy synthesized using the stir casting method significantly improved due to enhanced wettability between the immixtures. Similar findings using those as reinforcement are discussed and compared in Table 2.
The results of relevant and recent investigations were reviewed and presented in Table 2. It is found that the B4C and BN reinforcements significantly modify the properties of the materials. The present investigation focuses on improving the properties of Mg–Al–Zn alloy with B4C and BN reinforcements. From the experimental results, it is observed that Mg–Al–Zn alloy reinforced with 9 wt% of B4C and 3 wt% of BN improved hardness by 14.91%, compressive strength by 37.89%, yield strength by 74.63%, tensile strength by 28.94%, and corrosion resistance by 37.81%. It is observed that there are negligible changes in the density and porosity, which are increased by 0.03% and decreased by 0.01%, respectively.
This study aims to strengthen Mg–Al–Zn alloys using B4C and BN as ceramic-strengthening particulates. The Mg–Al–Zn alloy (91.35 wt% pure magnesium, 8.3 wt% Aluminium, 0.35 wt% Zinc) was cast and further strengthened; a stir casting method was used utilized to synthesize three kinds of Mg–Al–Zn/B4C/BN hybrid composites. Among the developed hybrid mixture, 9 wt% B4C/BN reinforced Mg–Al–Zn alloys hybrid composite exhibited the optimum results. Morphological studies ensured that there was good interfacial integrity between the Mg matrix and the hybrid ceramic reinforcement, as no voids or deboning occurred at the particle–matrix interface. It was also affirmed that the reduction in grain size in the matrix alloy was identified and ensured that they act as a strengthening mechanism of fabricated magnesium alloy intermixture. From the XRDA analysis that the presence of intermetallic components of Mg17Al12, MgB2, Mg2Si, Mg3BN3, MgO, B2O3, MgC2. EDAX analysis indicates that this hybrid intermixture blends Mg–Al–Si–Mn–B–N compositions, indicating improved mechanical properties. The significant outcomes of mechanical, corrosion, and hardness properties are furnished below.
Due to the presence of the Mg2Si interface and an increment in the proportional of strengthening particulates, the denseness of synthetic immixture substantially amplified to a minimum of 0.03%, and a reduction in porosity has been observed as 0.01% compared with monolithic magnesium alloy.
The mechanical properties such as hardness (14.91%), tensile strength (28.94%), and yield point (34%) of synthesized composites are significantly increased. On the other hand, the percentage elongation has decreased compared to unreinforced alloy.
The compressive strength (37.89%) of synthesized magnesium alloy hybrid composites has increased substantially because of heterogeneous deformation on the magnesium alloy matrix at the grain boundary.
The corrosion-resistant magnesium alloy hybrid composites increased to a maximum of (37.81%) as a consequence of the continuous beta phase along the alpha grain boundary.
The limitation of this study is preferred range of B4C is up to 9 wt%. The experimental results showed that the highest contribution of reinforcement (9 wt. %) outperformed in properties enhancement of Mg–Al–Zn alloy. As a further investigation, it can be observed that various low-density reinforcements can significantly improve the properties of Mg–Al–Zn alloys. With lower fuel consumption and CO2 emissions, functional materials such as aluminium, zinc, and other alloying elements are added to pure magnesium to reduce environmental impact.
The datasets used and analyzed during the current study are available from the corresponding author upon reasonable request.
Nie, K. B., Wang, X. J., Deng, K. K., Hu, X. S. & Wu, K. Magnesium matrix composite reinforced by nanoparticles—A review. J. Magnes. Alloys 9, 57–77. https://doi.org/10.1016/j.jma.2020.08.018 (2021).
Song, X., Bayati, P., Gupta, M., Elahinia, M. & Haghshenas, M. Fracture of magnesium matrix nanocomposites—A review. Int. J. Lightweight Mater. Manuf. 4, 67–98. https://doi.org/10.1016/j.ijlmm.2020.07.002 (2021).
de Velo, M. M. A. C. et al. Enhancing the mechanical properties and providing bioactive potential for graphene oxide/montmorillonite hybrid dental resin composites. Sci. Rep. 12, 10259–10259. https://doi.org/10.1038/s41598-022-13766-1 (2022).
Article ADS PubMed PubMed Central CAS Google Scholar
Pasha, M. B., Rao, R. N., Ismail, S. & Gupta, M. Microstructure, mechanical and ignition characteristics of Si3N4 reinforced magnesium matrix nanocomposites. Appl. Sci. 12, 6138. https://doi.org/10.3390/app12126138 (2022).
Pradeep, N. B. et al. Synthesis and characterization of mechanically alloyed nanostructured ternary titanium based alloy for bio-medical applications. J. Mater. Res. Technol. 16, 88–101. https://doi.org/10.1016/j.jmrt.2021.11.101 (2022).
Qiao, K. et al. Mg/ZrO(2) metal matrix nanocomposites fabricated by friction stir processing: microstructure, mechanical properties and corrosion behavior. Front. Bioeng. Biotechnol. 9, 605171–605171. https://doi.org/10.3389/fbioe.2021.605171 (2021).
Article PubMed PubMed Central Google Scholar
Huang, S.-J., Subramani, M. & Chiang, C.-C. Effect of hybrid reinforcement on microstructure and mechanical properties of AZ61 magnesium alloy processed by stir casting method. Comp. Commun. 25, 100772. https://doi.org/10.1016/j.coco.2021.100772 (2021).
Amalan, A. P. A., Sivaram, N. M., Bavatharani, C. & Ragupathy, D. A study on the effect of ageing heat treatment on hardness, tensile and corrosion behaviour of stir-cast AZ91D–5SiC–1Gr hybrid magnesium composite. Int. J. Metalcast. 16, 973–986. https://doi.org/10.1007/s40962-021-00656-x (2021).
Sun, Y. et al. Influence of GNPs and B4C reinforcements on mechanical, thermal and wear properties of magnesium matrix composite produced by powder metallurgy. J. Compos. Mater. 55, 3881–3891. https://doi.org/10.1177/00219983211031641 (2021).
Article ADS CAS Google Scholar
Kharb, S. S., Khatkar, S. K., Charak, A. & Thakur, A. Tribological investigation of AZ91/SiC magnesium hybrid composite under dry oil and nanofluids lubricating conditions. SILICON 13, 1313–1323. https://doi.org/10.1007/s12633-020-00520-3 (2020).
Khatkar, S. K., Verma, R., Kant, S. & Suri, N. M. Effect of reinforcements on the sliding wear behavior of self-lubricating AZ91D-SiC-Gr hybrid composites. Int. J. Surf. Eng. Interdiscipl. Mater. Sci. 10, 1–19. https://doi.org/10.4018/ijseims.2022010103 (2022).
Li, P., Tan, W., Gao, M. & Shi, K. Strengthening of the magnesium matrix composites hybrid reinforced by chemically oxidized carbon nanotubes and in situ Mg2Sip. J. Alloys Compd. 858, 157673. https://doi.org/10.1016/j.jallcom.2020.157673 (2021).
Huang, S.-J., Subramani, M. & Borodianskiy, K. Strength and ductility enhancement of AZ61/Al2O3/SiC hybrid composite by ECAP processing. Mater. Today Commun. 31, 103261. https://doi.org/10.1016/j.mtcomm.2022.103261 (2022).
Zhao, R. et al. Fabrication of magnesium-coated graphene and its effect on the microstructure of reinforced AZ91 magnesium-matrix composites. Adv. Comp. Hybrid Mater. 5, 504–512. https://doi.org/10.1007/s42114-021-00336-8 (2021).
Parthiban, K., Lakshmanan, P. & Gnanavelbabu, A. Experimental and theoretical yield strength of silicon carbide and hexagonal boron nitride reinforced Mg-Zn nanocomposites produced by the combined effects of ultrasonication and squeeze casting. SILICON 14, 8993–9007. https://doi.org/10.1007/s12633-022-01679-7 (2022).
Vairamuthu, J., Senthil Kumar, A., Sivakumar, G. D., Rajeshwaran, S. K. & Subbiah, R. Preparation and characterization of AZ63A/Boron Nitride composites using hybrid mechanical and ultrasonic assisted stir casting. Mater. Today 59, 1513–1519. https://doi.org/10.1016/j.matpr.2022.01.403 (2022).
Şenel, M. C. & Gürbüz, M. Synergistic effect of graphene/boron nitride binary nanoparticles on aluminum hybrid composite properties. Adv. Comp. Hybrid Mater. 4, 1248–1260. https://doi.org/10.1007/s42114-021-00209-0 (2021).
Paul, T., Zhang, C., Denis, N., Boesl, B. & Agarwal, A. Role of ultrasonic treatment on microstructure, mechanical and tribological behavior of 2D boron nitride reinforced aluminum composites. Mater. Sci. Eng. A 809, 140970. https://doi.org/10.1016/j.msea.2021.140970 (2021).
Ahmad, Z. & Khan, S. Mechanical characterization of LM25 alloy matrix composite reinforced with boron carbide. J. Compos. Mater. 55, 3151–3158. https://doi.org/10.1177/00219983211005513 (2021).
Article ADS CAS Google Scholar
Jadhav, P. R., Sridhar, B. R., Nagaral, M. & Harti, J. I. Mechanical behavior and fractography of graphite and boron carbide particulates reinforced A356 alloy hybrid metal matrix composites. Adv. Comp. Hybrid Mater. 3, 114–119. https://doi.org/10.1007/s42114-020-00143-7 (2020).
Mousavi, S. F., Sharifi, H., Tayebi, M., Hamawandi, B. & Behnamian, Y. Thermal cycles behavior and microstructure of AZ31/SiC composite prepared by stir casting. Sci. Rep. 12, 15191–15191. https://doi.org/10.1038/s41598-022-19410-2 (2022).
Article ADS PubMed PubMed Central CAS Google Scholar
Xiang, S. et al. Graphene nanoplatelets induced heterogeneous bimodal structural magnesium matrix composites with enhanced mechanical properties. Sci. Rep. 6, 38824–38824. https://doi.org/10.1038/srep38824 (2016).
Article ADS PubMed PubMed Central CAS Google Scholar
Kuldeep, B., Ravikumar, K. P., Pradeep, S. & Gopi, K. R. Effect of boron nitride and zirconium dioxide on mechanical behavior of Al7075 metal matrix hybrid composite. Mater. Res. Express 6, 036509. https://doi.org/10.1088/2053-1591/aaf36b (2018).
Article ADS CAS Google Scholar
Singh, H., Brar, G. S., Kumarand, H. & Aggarwal, V. Characterization and sustainability of boron carbide reinforced 7075 aluminum metal matrix composites. J. Green Eng. 10, 7857–7868 (2020).
Rajkumar, P. R., Kailasanathan, C., Senthilkumar, A., Selvakumar, N. & JohnRajan, A. Study on formability and strain hardening index: influence of particle size of boron carbide (B<sub>4</sub>C) in magnesium matrix composites fabricated by powder metallurgy technique. Mater. Res. Express 7, 016597. https://doi.org/10.1088/2053-1591/ab6c0b (2020).
Article ADS CAS Google Scholar
Polat, S., Sun, Y., Çevik, E., Colijn, H. & Turan, M. E. Investigation of wear and corrosion behavior of graphene nanoplatelet-coated B<sub>4</sub>C reinforced Al–Si matrix semi-ceramic hybrid composites. J. Compos. Mater. 53, 3549–3565. https://doi.org/10.1177/0021998319842297 (2019).
Article ADS CAS Google Scholar
Turan, M. E. et al. Effects of carbonaceous reinforcements on microstructure and corrosion properties of magnesium matrix composites. Mater. Chem. Phys. 218, 182–188. https://doi.org/10.1016/j.matchemphys.2018.07.050 (2018).
Turan, M. E., Sun, Y. & Akgul, Y. Mechanical, tribological and corrosion properties of fullerene reinforced magnesium matrix composites fabricated by semi powder metallurgy. J. Alloys Compd. 740, 1149–1158. https://doi.org/10.1016/j.jallcom.2018.01.103 (2018).
Chen, Y., Li, J., Yang, W., Gao, S. & Cao, R. Enhanced corrosion protective performance of graphene oxide-based composite films on AZ31 magnesium alloys in 3.5 wt% NaCl solution. Appl. Surf. Sci. 493, 1224–1235. https://doi.org/10.1016/j.apsusc.2019.07.101 (2019).
Article ADS CAS Google Scholar
Li, G. et al. Microstructure, mechanical properties and corrosion resistance of A356 aluminum/AZ91D magnesium bimetal prepared by a compound casting combined with a novel Ni-Cu composite interlayer. J. Mater. Process. Technol. 288, 116874. https://doi.org/10.1016/j.jmatprotec.2020.116874 (2021).
Mohan, P. & Manna, A. Fabrication and processing of bioabsorbable hybrid Zn/(Ag + Fe + Mg)-MMC on developed ultrasonic vibration-assisted argon atmosphere stir casting set-up. Arab. J. Sci. Eng. 47, 8361–8372. https://doi.org/10.1007/s13369-021-06205-2 (2021).
Ghasali, E. et al. Corrosion behavior and in-vitro bioactivity of porous Mg/Al2O3 and Mg/Si3N4 metal matrix composites fabricated using microwave sintering process. Mater. Chem. Phys. 225, 331–339. https://doi.org/10.1016/j.matchemphys.2019.01.007 (2019).
Jalilvand, M. M. & Mazaheri, Y. Effect of mono and hybrid ceramic reinforcement particles on the tribological behavior of the AZ31 matrix surface composites developed by friction stir processing. Ceram. Int. 46, 20345–20356. https://doi.org/10.1016/j.ceramint.2020.05.123 (2020).
Liu, S., Wang, Y., Muthuramalingam, T. & Anbuchezhiyan, G. Effect of B4C and MOS2 reinforcement on micro structure and wear properties of aluminum hybrid composite for automotive applications. Compos. B Eng. 176, 107329. https://doi.org/10.1016/j.compositesb.2019.107329 (2019).
Banerjee, S., Poria, S., Sutradhar, G. & Sahoo, P. Nano-indentation and corrosion characteristics of ultrasonic vibration assisted stir-cast AZ31–WC–graphite nano-composites. Int. J. Metalcast. 15, 1058–1072. https://doi.org/10.1007/s40962-020-00538-8 (2020).
Gobara, M., Shamekh, M. & Akid, R. Improving the corrosion resistance of AZ91D magnesium alloy through reinforcement with titanium carbides and borides. J. Magnes. Alloys 3, 112–120. https://doi.org/10.1016/j.jma.2015.03.002 (2015).
Qiao, K. et al. Effect of multi-pass friction stir processing on the microstructure evolution and corrosion behavior of ZrO2/AZ31 magnesium matrix composite. J. Market. Res. 18, 1166–1179. https://doi.org/10.1016/j.jmrt.2022.02.127 (2022).
Seetharam, R., Subbu, S. K., Davidson, M. J., Ramkumar, K. R. & Madhukar, P. Influence of reinforcement particles on dynamically recrystallized grain of hot upset sintered Al-B4C composites. J. Mater. Eng. Perform. https://doi.org/10.1007/s11665-022-06955-6 (2022).
Yang, L. et al. Influence of pH value on the microstructure and corrosion behavior of carbon fiber reinforced magnesium matrix composites. J. Market. Res. 17, 412–424. https://doi.org/10.1016/j.jmrt.2022.01.031 (2022).
Matta, A. K., Koka, N. S. S. & Devarakonda, S. K. Recent studies on particulate reinforced AZ91 magnesium composites fabricated by Stir casting—A review. J. Mech. Energy Eng. 4, 115–126. https://doi.org/10.30464/jmee.2020.4.2.115 (2020).
Guo, Y. et al. Microstructure and properties of in-situ synthesized ZrC-Al3Zr reinforced composite coating on AZ91D magnesium alloy by laser cladding. Surf. Coat. Technol. 334, 471–478. https://doi.org/10.1016/j.surfcoat.2017.12.007 (2018).
Zhihui, L. et al. Oxidation resistance of magnesium alloyed by different elements: A brief review. Res. Appl. Mater. Sci. 3, 18–25 (2022).
Dong, B.-X. et al. The synthesis, structure, morphology characterizations and evolution mechanisms of nanosized titanium carbides and their further applications. Nanomaterials (Basel) 9, 1152. https://doi.org/10.3390/nano9081152 (2019).
Ramadoss, N., Pazhanivel, K. & Anbuchezhiyan, G. Synthesis of B4C and BN reinforced Al7075 hybrid composites using stir casting method. J. Market. Res. 9, 6297–6304. https://doi.org/10.1016/j.jmrt.2020.03.043 (2020).
Chand, S. & Chandrasekhar, P. Influence of B4C/BN on solid particle erosion of Al6061 metal matrix hybrid composites fabricated through powder metallurgy technique. Ceram. Int. 46, 17621–17630. https://doi.org/10.1016/j.ceramint.2020.04.064 (2020).
Vignesh Kumar, V., Raja, K., Chandra Sekar, V. S. & Ramkumar, T. Thrust force evaluation and microstructure characterization of hybrid composites (Al7075/B4C/BN) processed by conventional casting technique. J. Braz. Soc. Mech. Sci. Eng. https://doi.org/10.1007/s40430-019-1728-5 (2019).
Dirisenapu, G., Dumpala, L. & Reddy, S. P. Dry sliding tribological behavior of Al7010/B4C/BN hybrid metal matrix nanocomposites prepared by ultrasonic-assisted stir casting. Trans. Indian Inst. Met. 74, 149–158. https://doi.org/10.1007/s12666-020-02128-y (2020).
Ayyanar, S., Gnanavelbabu, A., Rajkumar, K. & Loganathan, P. Studies on high temperature wear and friction behaviour of AA6061/B4C/hBN hybrid composites. Met. Mater. Int. 27, 3040–3057. https://doi.org/10.1007/s12540-020-00710-z (2020).
Dirisenapu, G., Reddy, S. P. & Dumpala, L. The effect of B4C and BN nanoparticles on the mechanical and microstructural properties of Al7010 hybrid metal matrix. Mater. Res. Exp. 6, 105089. https://doi.org/10.1088/2053-1591/ab3d6d (2019).
Chand, S. et al. Effect of Three-Body Abrasion Wear Behavior on B4C/BN-reinforced Al6061 Alloy Fabricated Through Powder Metallurgy Method in Recent Advances in Thermofluids and Manufacturing Engineering 493–503 (Springer Nature Singapore, 2022).
Department of Mechanical Engineering, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Chennai, 602105, Tamil Nadu, India
Petroleum and Chemical Engineering, Faculty of Engineering, Universiti Teknologi Brunei, BE1410, Bandar Seri Begawan, Brunei Darussalam
Nabisab Mujawar Mubarak & Rama Rao Karri
Graphene & Advanced 2D Materials Research Group (GAMRG), School of Engineering and Technology, Sunway University, No. 5, Jalan University, Bandar Sunway, 47500, Petaling Jaya, Selangor, Malaysia
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G.A: Conceptualization, original draft preparation: Methodology and Formal analysis: G.A.; Review and editing manuscript: N.M.M., R.R.K. and M.K.. All authors have read and agreed to the published version of the manuscript.
Correspondence to Gnanasambandam Anbuchezhiyan or Nabisab Mujawar Mubarak.
The authors declare no competing interests.
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Anbuchezhiyan, G., Mubarak, N.M., Karri, R.R. et al. A synergistic effect on enriching the Mg–Al–Zn alloy-based hybrid composite properties. Sci Rep 12, 20053 (2022). https://doi.org/10.1038/s41598-022-24427-8
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